منابع مشابه
56-74 Heck
PHILOSOPHY VII 1999 1. Opening WHAT IS THE EPISTEMOLOGICAL STATUS OF OUR KNOWledge of the truths of arithmetic? Are they analytic, the products of pure reason, as Leibniz held? Or are they high-level empirical truths that we know only a posteriori, as some empiricists, particularly Mill, have held? Or was Kant right to say that, although our knowledge that ‘5+7=12’ depends essentially upon intu...
متن کاملEnantioselective oxidative boron Heck reactions.
This review highlights the use of the oxidative boron Heck reaction in enantioselective Heck-type couplings. The enantioselective oxidative boron Heck reaction overcomes several limitations of the traditional Pd(0)-catalysed Heck coupling and has subsequently allowed for intermolecular couplings of challenging systems such as cyclic enones, acyclic alkenes, and even site selectively on remote a...
متن کاملMechanisms of the Mizoroki–Heck Reaction
The palladium-catalysed Mizoroki–Heck reaction is the most efficient route for the vinylation of aryl/vinyl halides or triflates. This reaction, in which a C C bond is formed, proceeds in the presence of a base (Scheme 1.1) [1, 2]. Nonconjugated alkenes are formed in reactions involving cyclic alkenes (Scheme 1.2) [1e, 2a,c,e,g] or in intramolecular reactions (Scheme 1.3) [2b,d–g] with creation...
متن کاملNew Homogeneous And Robust Catalyst for Heck and Suzuki Reactions
In this work, different ethyl 2,4-dioxo-4-arylbutanoate derivatives were prepared and evaluated for their Src Kinase inhibitory activity. For this purpose, the appropriate substituted acetophenone derivatives reacted with diethyl oxalate in the presence of sodium ethoxide in dried ethanol to give the corresponding products. All compounds showed moderate activities comparing with staurosporine a...
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ژورنال
عنوان ژورنال: Boletín de Arte
سال: 2017
ISSN: 0211-8483
DOI: 10.24310/bolarte.2014.v0i35.3510